Quote:
Originally Posted by Flyingwedge
It's St. Joseph's Catholic Church in La Puente:
Nov 23, 1908, Los Angeles Times @ Newspapers.com
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Great ID,
Flyingwedge! You beat me to it.

To answer
e_r, the "mansion'" at far left in the OP photo is the Hotel Rowland (1886-1955), formerly located at the northeast corner of 2nd and Main in today's La Puente.
eBay
Here is a view of the front of the hotel as viewed from 2nd Street, c.1910.
LAPL
Old St. Joseph's stood on the site of today's La Puente City Hall, which fronts on Central, so from the vantage point of the photographer in the OP, we would be viewing the Hotel Rowland from the southeast here.
And to answer both
Scott Charles and
Flyingwedge, I found a photo
on the Homestead Museum site that was used for the inset in the 1908 LA Times article. The Homestead caption, however, misidentifies the depicted "priest." Presiding at the dedication of St. Joseph's in Puente on November 22, 1908, was the Right Rev. Thomas J. Conaty, Diocesan Bishop of Los Angeles from 1903 to his death in 1915.
-JScott